Crystal structure, optical properties, spectroscopic characterization and density functional theory studies of a new rhodium(i)-imidazolidin-2-ylidene complexes: Synthesis, characterization and cytotoxic properties

Emine Özge Karaca,Osman Çiftçi,İlknur Özdemir,Hande Karabıyık,Hasan Karabıyık, Nevin Gürbüz,İsmail Özdemir,Lamjed Mansour,Arfaoui Youssef,Naceur Hamdi

Inorganica Chimica Acta（2022）

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摘要

•A series of [RhCl(COD)(NHC)] complexes were synthesized and characterized.•The cytotoxic properties of the rhodium(I)-NHC complexes have been assessed in various human cancer lines, including cisplatin-sensitive and resistant cells. These complexes have been highlighted cancer therapeutic agent with unique structures and functions.

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关键词

Antitumor activity,Imidazolidine-2-ylidene,N-heterocyclic carbene,Rhodium complexes,Crystal structure,DFT calculations,Optical properties,Hirshfeld Surface analysis (HS)

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